Organic-inorganic hybrid complexes of Lead(II) of sterically demanding heterocyclic β-diketones and flexible N-protected amino acids
IR@NISCAIR: CSIR-NISCAIR, New Delhi - ONLINE PERIODICALS REPOSITORY (NOPR)
View Archive InfoField | Value | |
Title |
Organic-inorganic hybrid complexes of Lead(II) of sterically demanding heterocyclic β-diketones and flexible N-protected amino acids
|
|
Creator |
Maheshwari, Karuna
Saxena, Sanjiv Jain, Asha |
|
Subject |
Lead(II) isopropoxide
Heterocyclic β-diketones N-protected amino acids Distorted trigonal bipyramidal geometry |
|
Description |
202-208
A new set of organic-inorganic hybrid complexes of lead(II) of sterically demanding heterocyclic β-diketones and flexible N-protected amino acids of composition Pb[RC(O)<img src='http://nopr.niscair.res.in/jinfo/ijcafeb21.gif' border=0>CH<sub>3</sub>][<img src="http://www.niscair.res.in/jinfo/equation143.gif" alt="" border="0" />CHR'COO] (where R = C<sub>6</sub>H<sub>5</sub>, p-ClC<sub>6</sub>H<sub>4</sub>, CH<sub>3 </sub>and R’ = CH(CH<sub>3</sub>)C<sub>2</sub>H<sub>5, </sub>CH<sub>2</sub>CH(CH<sub>3</sub>)<sub>2</sub> and CH(CH<sub>3</sub>)<sub>2 </sub>) has been generated by the reactions of freshly prepared lead isopropoxide with sterically demanding heterocyclic β-diketones (LH) and flexible N-protected amino acids (AH) in 1:1:1 molar ratio in refluxing dry benzene . These lead(II) complexes of mixed organic ligands have been characterized on the basis of physico-chemical and spectroscopic studies. |
|
Date |
2021-02-11T06:53:29Z
2021-02-11T06:53:29Z 2021-02 |
|
Type |
Article
|
|
Identifier |
0975-0975(Online); 0376-4710(Print)
http://nopr.niscair.res.in/handle/123456789/56201 |
|
Language |
en_US
|
|
Rights |
<img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
|
|
Publisher |
NISCAIR-CSIR, India
|
|
Source |
IJC-A Vol.60A(02) [February 2021]
|
|