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Production of biodiesel from high free fatty acids content Jatropha curcas oil using environment affable K–Mg composite catalyst

IR@CIMFR: CSIR-Central Institute of Mining and Fuel Research, Dhanbad

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Title Production of biodiesel from high free fatty acids content Jatropha curcas oil using environment affable K–Mg composite catalyst
 
Creator Sahu, Gajanan
Saha, Sujan
Datta, Sudipta
Chavan, Prakash D.
Chauhan, Vishal
Gupta, Pavan K.
 
Subject Coal Gesification
 
Description Worldwide chemical industries are concerned towards pollution‐free and green processes. In this regard, alternative energy resource having minimal pollutant and toxins emission would be preferred. Jatropha curcas (JCO) is one of the important and alternative feedstock for biodiesel production. In the present work, JCO with higher (5.5%) free fatty acid (FFA) was used for transesterification using K–Mg composite catalyst. It found that 1:2 ratio of K/Mg was the best combination for efficient conversion of JCO to corresponding methyl esters. Physico‐chemical characterization of this novel catalyst exhibited improved surface area with adequate porosity as well as basicity helping its exceptional catalytic activity. Under optimum condition, 99.5% conversion was achieved using 10:1 ratio of methanol to JCO for 3 h at 70°C using 6 wt% of catalyst. This catalyst was truly heterogeneous in nature and almost retained its activity for subsequent re‐using for next five batches. The developed catalyst is highly efficient and greener in terms of lesser leaching behaviour and retaining the basic catalytic sites in the course of transesterification. The fuel properties of the biodiesel are fully complied with ASTM protocols; thus, research findings are significant to fulfil the demand of biodiesel in present scenario. Supporting Information
 
Publisher John Wiley
 
Date 2021-02-04
 
Type Article
PeerReviewed
 
Relation https://doi.org/10.1002/apj.2620
http://cimfr.csircentral.net/2343/
 
Identifier Sahu, Gajanan and Saha, Sujan and Datta, Sudipta and Chavan, Prakash D. and Chauhan, Vishal and Gupta, Pavan K. (2021) Production of biodiesel from high free fatty acids content Jatropha curcas oil using environment affable K–Mg composite catalyst. Asian Pacific Journal of Chemical Engineering.