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Comparison of CO2 gasification reactivity and kinetics: petcoke, biomass and high ash coal

IR@CIMFR: CSIR-Central Institute of Mining and Fuel Research, Dhanbad

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Title Comparison of CO2 gasification reactivity and kinetics: petcoke, biomass and high ash coal
 
Creator Kumari, Neelam
Saha, Sujan
Sahu, Gajanan
Chauhan, Vishal
Roy, Rupak
Datta, Sudipta
Chavan, Prakash D.
 
Subject Coal Gesification
 
Description It is desirable to exploit biomass energy along with coal and petcoke through gasification, and understanding the differencesbetween petroleum coke (petcoke), coal and biomass gasification behaviour becomes very essential. Consequently, presentinvestigation compares gasification components of petcoke, sawdust and high ash coal with their physico-chemical propertiesunder isothermal conditions in CO2atmosphere in the temperature range of 1173–1623 K. Physico-chemical characterisationincludes proximate and ultimate analyses, porous structure analysis by Brunauer-Emmett-Teller (BET) surface area from nitro-gen (N2) adsorption isotherm, ash composition analysis and ash fusion temperature. The effects of temperature and nature ofdifferent solid fuels on gasification reactivity have been discussed. Gasification kinetics has been investigated using two nth-order kinetic models, such as homogeneous model (HM) and shrinking core model (SCM). Influence of diffusion resistance ongasification behaviour of different solid fuels is also reported. Thus, the present study will be helpful to realise the effects of highash in gasification behaviour as well as in designing and modelling of the suitable gasifier and to establish optimum gasificationconditions for petcoke, biomass and high ash coal
 
Publisher Springer
 
Date 2020-07
 
Type Article
PeerReviewed
 
Relation https://DOI 10.1007/s13399-020-00882-z
http://cimfr.csircentral.net/2346/
 
Identifier Kumari, Neelam and Saha, Sujan and Sahu, Gajanan and Chauhan, Vishal and Roy, Rupak and Datta, Sudipta and Chavan, Prakash D. (2020) Comparison of CO2 gasification reactivity and kinetics: petcoke, biomass and high ash coal. Biomass Conversion and Biorefinery. ISSN ISSN 2190-6815