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Characterization of lignite deposits of Barmer Basin, Rajasthan: insights from mineralogical and elemental analysis

IR@CIMFR: CSIR-Central Institute of Mining and Fuel Research, Dhanbad

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Title Characterization of lignite deposits of Barmer Basin, Rajasthan: insights from mineralogical and elemental analysis
 
Creator Gopinathan, P.
Maity, Sudip
Saha, Sujan
 
Subject Coal Characterisation
 
Description The geochemistry of fly ash produced from the combustion of coal at thermal power plants presents a significant challenge for disposal and environmental impact due to its complex mineralogical and elemental composition. The objective of this study was to investigate the mineralogical and elemental distribution of thirty lignite samples from the Barmer Basin using advanced techniques such as X-ray diffraction (XRD), X-ray fluorescence spectrometry (XRF) and inductively coupled plasma mass spectrometry (ICP-MS). XRD analysis revealed the presence of minerals such as haematite (Fe2O3), nepheline, anhydrite, magnesite, andalusite, spinel and anatase. Other minor minerals included albite, siderite, periclase, calcite, mayenite, hauyne, pyrite, cristobalite, quartz, nosean and kaolinite. XRF analysis demonstrated that the most abundant elements in the Barmer Basin lignite ash were iron oxide (Fe2O3), sulphur oxide (SO3), calcium oxide (CaO), and quartz (SiO2) followed by minor traces of toxic oxides (SrO, V2O5, NiO, Cr2O3, Co2O3, CuO) that are known to have adverse effects on human health and the environment. The rare earth element (REE) composition showed higher concentrations of Tb, Dy, Ho, Er, Tm, Yb, Lu, Y and Sc at the Giral and lower concentrations at Sonari mine. The Barmer lignites recorded higher concentration of trace elements such as V, Cr, Co, Ni, Cu and Sr while lower concentration of Rb, Cs, Ba, Pb, As, Th and U were observed within optimal range. The study findings revealed the predominant mineral concentration, elemental makeup, trace elements and rare earth elements associated with lignite reserves in the Barmer Basin.
 
Publisher springer
 
Date 2023-06-16
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://cimfr.csircentral.net/2600/1/Characterization%20of%20lignite%20deposits%20of%20Barmer%20Basin%20Rajasthan%20insights%20from%20mineralogical%20and%20elemental%20analysis%20%281%29.pdf
Gopinathan, P. and Maity, Sudip and Saha, Sujan (2023) Characterization of lignite deposits of Barmer Basin, Rajasthan: insights from mineralogical and elemental analysis. Environmental Geochemistry and Health, 45. ISSN 0269-4042
 
Relation http://cimfr.csircentral.net/2600/