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1,3-Dipolar cycloadditions. Part XXI: Catalytic effects of Lewis acids on 1,3-dipolar cycloaddition of <i style="">C</i>-(4-chlorophenyl)-<i style="">N</i>-phenyl nitrone to benzylidene acetophenone

IR@NISCAIR: CSIR-NISCAIR, New Delhi - ONLINE PERIODICALS REPOSITORY (NOPR)

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Field Value
 
Creator Acharjee, Nivedita
Banerji, Avijit
Prangé, Thierry
 
Date 2011-06-07T09:44:25Z
2011-06-07T09:44:25Z
2011-06
 
Identifier 0975-0983(Online); 0376-4699(Print)
http://hdl.handle.net/123456789/11911
 
Description 835-842
The normal electron demand reaction of <i style="">C</i>-chlorophenyl-<i style="">N</i>-phenyl nitrone with benzylidene acetophenone and the effects of mild Lewis acid catalysts like metal triflates and magnesium bromide on the reaction rate are reported. Frontier molecular orbital energies are calculated to rationalise the regioselectivity of the cycloaddition.
 
Language en_US
 
Publisher NISCAIR-CSIR, India
 
Rights <img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
 
Source IJC-B Vol.50B(06) [June 2011]
 
Subject 1,3-Dipolar cycloadditions
Nitrone
Benzylidene acetophenone
Lewis acid catalyst
 
Title 1,3-Dipolar cycloadditions. Part XXI: Catalytic effects of Lewis acids on 1,3-dipolar cycloaddition of <i style="">C</i>-(4-chlorophenyl)-<i style="">N</i>-phenyl nitrone to benzylidene acetophenone
 
Type Article