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Field Value
 
Creator Tintula, KK
Sahu, AK
Shahid, A
Pitchumani, S
Sridhar, P
Shukla, AK
 
Subject Electrochemistry; Materials Science
 
Description In situ polymerization of 3,4-ethylenedioxythiophene with sol-gel-derived mesoporous carbon (MC) leading to a new composite and its subsequent impregnation with Pt nanoparticles for application in polymer electrolyte fuel cells (PEFCs) is reported. The composite exhibits good dispersion and utilization of platinum nanoparticles akin to other commonly used microporous carbon materials, such as carbon black. Pt-supported MC-poly(3,4-ethylenedioxythiophene) (PEDOT) composite also exhibits promising electrocatalytic activity toward oxygen reduction reaction, which is central to PEFCs. The PEFC with Pt-loaded MC-PEDOT support exhibits 75% of enhancement in its power density in relation to the PEFC with Pt-loaded pristine MC support while operating under identical conditions. It is conjectured that Pt-supported MC-PEDOT composite ameliorates PEFC performance/durability on repetitive potential cycling. (C) 2010 The Electrochemical Society. [DOI: 10.1149/1.3486172] All rights reserved.
 
Publisher ELECTROCHEMICAL SOC INCPENNINGTON65 SOUTH MAIN STREET, PENNINGTON, NJ 08534 USA
 
Date 2011-09-20T11:59:54Z
2011-09-20T11:59:54Z
2010
 
Type Article
 
Identifier JOURNAL OF THE ELECTROCHEMICAL SOCIETY
0013-4651
http://hdl.handle.net/123456789/11387
 
Language English