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Field Value
 
Creator Suresh, M
Mandal, AK
Saha, S
Suresh, E
Mandoli, A
Di Liddo, R
Parnigotto, PP
Das, A
 
Subject Chemistry
 
Description A newly synthesized azine-based receptor (L) is found to show remarkable specificity toward the Hg(2+) ion in aqueous media over other metal ions. Coordination of L to Hg(2+) induces a detectable change in color and a turn-on fluorescence response. Restricted C=N isomerization of the azine moieties in the excited state as well as the Photoinduced Electron Transfer (PET) involving the lone pair of electrons of N(1)/N(2) on coordination of L to the Hg(2+) ion account for the turn-on fluorescence response. This reagent could be used for imaging the accumulation of Hg(2+) ions in Epithelial cell line KB 31 cells.
 
Publisher AMER CHEMICAL SOCWASHINGTON1155 16TH ST, NW, WASHINGTON, DC 20036 USA
 
Date 2011-09-20T12:03:05Z
2011-09-20T12:03:05Z
2010
 
Type Article
 
Identifier ORGANIC LETTERS
1523-7060
http://hdl.handle.net/123456789/12165
 
Language English