Metadata of CSIR Papers
View Archive Info| Field | Value | |
| Creator |
Patil, RD
Joshi, G Adimurthy, S |
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| Subject |
Engineering
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| Description |
HBr-H(2)O(2) is efficiently activated in water under mild conditions, allowing the bromohydroxylation of various styrenes. HBr-H(2)O(2) is more economic and easy to handle and offers sufficiently high regioselectivity (100%) for bromohydrin synthesis. Further activation of bromohydrin with a catalytic amount of HBr (50 mol %) and H(2)O(2) in water affords alpha-bromoketones in moderate to good yields in a single step. Oxidation of benzylic/secondary alcohols to the corresponding carbonyl compounds has been achieved with the HBr (10 mol %) and H(2)O(2) efficiently in aqueous dioxane under ambient conditions.
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| Publisher |
AMER CHEMICAL SOCWASHINGTON1155 16TH ST, NW, WASHINGTON, DC 20036 USA
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| Date |
2011-09-20T12:03:11Z
2011-09-20T12:03:11Z 2010 |
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| Type |
Article
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| Identifier |
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
0888-5885 http://hdl.handle.net/123456789/12213 |
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| Language |
English
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