Metadata of CSIR Papers
View Archive Info| Field | Value | |
| Creator |
Mahendrasinh, Z
Kumar, SB Suresh, E Ribas, J |
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| Subject |
Chemistry
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| Description |
A new pyridylpyrazole-containing tetradentate ligand, namely N,N-bis(3,5-dimethylpyrazol-1-ylmethyl)aminomethylpyridine (L), and two of its binuclear azido-bridged complexes, [Ni(2)(L)(2)(N(3))(2)](ClO(4))(2)center dot 2EtOH (1) and [Cu(2)(L)(2)(N(3))(2)](ClO(4))(2) (2), have been synthesized and characterized by physico-chemical and spectroscopic methods. The crystal structures of both complexes are reported. Each metal atom in the complexes has a MN(6) coordination environment with distorted octahedral geometry. Variable-temperature magnetic susceptibility measurements for complex (1) show typical antiferromagnetic behavior with J value -84.5 +/- A 1.3 cm(-1), whereas complex (2) has no magnetic interactions.
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| Publisher |
SPRINGERDORDRECHTVAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS
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| Date |
2011-09-20T12:03:12Z
2011-09-20T12:03:12Z 2010 |
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| Type |
Article
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| Identifier |
TRANSITION METAL CHEMISTRY
0340-4285 http://hdl.handle.net/123456789/12219 |
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| Language |
English
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