Metadata of CSIR Papers
View Archive Info| Field | Value | |
| Creator |
Das, P
Ghosh, A Das, A |
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| Subject |
Chemistry
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| Description |
A rare example of a reversible recognition of Nd(3+) by a newly synthesized molecular receptor (L(1)), having a diazo group as the reporter functionality, is reported. Studies revealed that this receptor eventually forms a [Nd(3+)](2)L(1) type complex, through the formation of the intermediate complex [Nd(3+)]center dot L(1) following a two-step equilibrium process. Respective equilibrium constants for two successive processes were evaluated based on data obtained from the systematic fluorescence titration. Formation of [Nd(3+)](2)L(1) caused a detectable change in color, and associated affinity constants were also evaluated from spectrophotometric titration data. A rather unusual binding mode of L(1) for Nd(3+) ion is established by various spectroscopic studies. The remarkable specificity of L(1) for Nd(3+), constitutes a rare example of a highly selective receptor for this ion in the presence of excess of all other lanthanide ions.
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| Publisher |
AMER CHEMICAL SOCWASHINGTON1155 16TH ST, NW, WASHINGTON, DC 20036 USA
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| Date |
2011-09-20T12:03:13Z
2011-09-20T12:03:13Z 2010 |
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| Type |
Article
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| Identifier |
INORGANIC CHEMISTRY
0020-1669 http://hdl.handle.net/123456789/12224 |
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| Language |
English
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