Metadata of CSIR Papers
View Archive Info| Field | Value | |
| Creator |
Dabbawala, AA
Jasra, RV Bajaj, HC |
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| Subject |
Chemistry
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| Description |
The regioselective hydroformylation of vinyl acetate catalyzed by rhodium complex of monodentate phosphite ligand, tri-1-naphthylphosphite P(ONp)(3), was investigated. The P(ONp)(3) ligand exhibited a considerable impact on the rate and selectivity of hydroformylation of vinyl acetate, notably high turnover frequency (up to 11,520 h(-1)) with excellent regioselectivity (99%) to the preferred branched aldehyde and high selectivity to aldehyde (93%). Significant results with the substrate having less reactive character toward hydroformylation and practically easy accessibility of the ligand (synthesized from inexpensive compound, 1-naphthol) make this system very attractive. (C) 2010 Elsevier B.V. All rights reserved.
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| Publisher |
ELSEVIER SCIENCE BVAMSTERDAMPO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS
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| Date |
2011-09-20T12:03:20Z
2011-09-20T12:03:20Z 2010 |
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| Type |
Article
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| Identifier |
CATALYSIS COMMUNICATIONS
1566-7367 http://hdl.handle.net/123456789/12283 |
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| Language |
English
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