Metadata of CSIR Papers
View Archive Info| Field | Value | |
| Creator |
Sen, A
Ganguly, B |
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| Subject |
Chemistry
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| Description |
A Computational (B3LYP/6-31G* and MP2/6-31G*) study shows that electrostatic interaction is controlling the pi-facial selectivity for the addition of peracid and diazomethane to 5,6-cis,exo-disubstituted bicyclic[2.2.2]oct-2-enes (1). The nitrogen centre of diazomethane which does not participate in bond formation governs the pi-face selectivity in 1,3-dipolar cycloaddition reactions with 1. The calculated results show that Cieplak model is less important in controlling the face selectivity in these cases. (C) 2009 Elsevier Ltd. All rights reserved.
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| Publisher |
PERGAMON-ELSEVIER SCIENCE LTDOXFORDTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
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| Date |
2011-09-20T12:03:25Z
2011-09-20T12:03:25Z 2010 |
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| Type |
Article
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| Identifier |
TETRAHEDRON LETTERS
0040-4039 http://hdl.handle.net/123456789/12320 |
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| Language |
English
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