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Mercury(II) chloride-mediated cyclization - Rearrangement of O-propargylglycolaldehyde dithioacetals to 3-pyranone dithioketals: An expeditious access to 3-pyranones

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Title Mercury(II) chloride-mediated cyclization - Rearrangement of O-propargylglycolaldehyde dithioacetals to 3-pyranone dithioketals: An expeditious access to 3-pyranones
 
Creator Ghorai, S
Bhattacharjya, A
 
Subject Chemistry, Organic
 
Description O-Propargyl glycolaldehyde dithioacetals undergo a unique cyclization-rearrangement in the presence of mercuric chloride and calcium carbonate to afford 3-pyranones exclusively or along with 2,5-dihydrofuran-3-carboxaldehydes via their dithioketals and dithioacetals.
 
Publisher AMER CHEMICAL SOCWASHINGTON1155 16TH ST, NW, WASHINGTON, DC 20036 USA
 
Date 2011-09-20T12:12:00Z
2011-09-20T12:12:00Z
2005
 
Type Article
 
Identifier ORGANIC LETTERS
1523-7060
http://hdl.handle.net/123456789/14080
 
Language English