General route to 4a-methylhydrofluorene diterpenoids: Total syntheses of (+/-)-taiwaniaquinones D and H, (+/-)-taiwaniaquinol B, (+/-)-dichroanal B, and (+/-)-dichroanone
Metadata of CSIR Papers
View Archive Info| Field | Value | |
| Title |
General route to 4a-methylhydrofluorene diterpenoids: Total syntheses of (+/-)-taiwaniaquinones D and H, (+/-)-taiwaniaquinol B, (+/-)-dichroanal B, and (+/-)-dichroanone
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| Creator |
Banerjee, M
Mukhopadhyay, R Achari, B Banerjee, AK |
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| Subject |
Chemistry, Organic
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| Description |
A general and convergent route for the synthesis of the 4a-methylhydrofluorene diterpenoids has been established through a common hexahydrofluorenone intermediate (10) obtained via Pd(0)-catalyzed reductive cyclization of a substituted 2-(2-bromobenzyl) methylene cyclohexane (13). The strategy has been successfully utilized for the synthesis of (+/-)-taiwaniaquinones D (3) and H (5), (+/-)-taiwaniaquinol B (1), (+/-)-dichroanal B (7), and (+/-)-dichroanone (8).
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| Publisher |
AMER CHEMICAL SOCWASHINGTON1155 16TH ST, NW, WASHINGTON, DC 20036 USA
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| Date |
2011-09-20T12:12:17Z
2011-09-20T12:12:17Z 2006 |
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| Type |
Article
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| Identifier |
JOURNAL OF ORGANIC CHEMISTRY
0022-3263 http://hdl.handle.net/123456789/14203 |
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| Language |
English
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