Divergent cycloaddition and ring-closing metathesis approaches to indolizidine and pyrrolo[1,2-a]azepine skeletons from a chiral precursor: An expeditious route to (-)-8-epi-swainsonine triacetate
Metadata of CSIR Papers
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Title |
Divergent cycloaddition and ring-closing metathesis approaches to indolizidine and pyrrolo[1,2-a]azepine skeletons from a chiral precursor: An expeditious route to (-)-8-epi-swainsonine triacetate
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Creator |
Nath, M
Mukhopadhyay, R Bhattacharjya, A |
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Subject |
Chemistry, Organic
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Description |
A divergent strategy for the synthesis of diverse azabicyclic ring systems has been developed in which a chiral N-allylpyrrolidine derivative, obtained from a carbohydrate precursor was converted to (-)-8-epi-swainsonine triacetate by RCM and to a pyrrolo[1,2-a]azepine derivative and a 3-hydroxymethyl-substituted indolizidine by N-allylcarbohydrate nitrone and nitrile oxide cycloadditions.
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Publisher |
AMER CHEMICAL SOCWASHINGTON1155 16TH ST, NW, WASHINGTON, DC 20036 USA
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Date |
2011-09-20T12:12:21Z
2011-09-20T12:12:21Z 2006 |
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Type |
Article
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Identifier |
ORGANIC LETTERS
1523-7060 http://hdl.handle.net/123456789/14239 |
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Language |
English
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