Stereoselective synthesis of chiral oxepanes and pyrans through intramolecular nitrone cycloaddition in organized aqueous media
Metadata of CSIR Papers
View Archive Info| Field | Value | |
| Title |
Stereoselective synthesis of chiral oxepanes and pyrans through intramolecular nitrone cycloaddition in organized aqueous media
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| Creator |
Chatterjee, A
Bhattacharya, PK |
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| Subject |
Chemistry, Organic
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| Description |
A highly stereoselective surfactant-catalyzed intramolecular nitrone (formed by dehydration in water) cycloaddition in aqueous media leading to exclusive formation of a single isomer is reported. Either oxepane or pyran is formed from 3-O-allyl furanoside derivatives, which constitute the framework of a large number of biologically active compounds. Therefore, the environmentally friendly, efficient, and highly stereoselective syntheses of these chiral intermediates are still a meaningful pursuit.
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| Publisher |
AMER CHEMICAL SOCWASHINGTON1155 16TH ST, NW, WASHINGTON, DC 20036 USA
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| Date |
2011-09-20T12:12:22Z
2011-09-20T12:12:22Z 2006 |
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| Type |
Article
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| Identifier |
JOURNAL OF ORGANIC CHEMISTRY
0022-3263 http://hdl.handle.net/123456789/14242 |
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| Language |
English
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