2-(Naphthyl-⍺-azo)imidazole complexes of manganese(II). Single crystal X-ray structure of [Mn(⍺-NaiEt)₂(NCS)₂] (⍺-NaiEt = 1-ethyl-2-(naphthyl-⍺-azo)imidazole)
IR@NISCAIR: CSIR-NISCAIR, New Delhi - ONLINE PERIODICALS REPOSITORY (NOPR)
View Archive Info| Field | Value | |
| Creator |
Bhunia, P
Sarker, K K Lin, C–N Lu, T–H Sinha, C |
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| Date |
2008-04-17T09:42:15Z
2008-04-17T09:42:15Z 2007-04 |
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| Identifier |
0376-4710
http://hdl.handle.net/123456789/1049 |
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| Description |
576-581
Azido/thiocyanato-manganese(II)-naphthylazoimidazole complexes, [Mn(⍺-NaiR)₂(X)₂] (⍺-NaiEt = 1-alkyl-2-(naphthyl-⍺-azo)imidazole; X = N₃-, NCS-), have been characterized. Microanalytical, spectral (FT-IR, UV-vis) and magnetic (bulk and EPR) data have been used to establish the molecular and electronic structure of the complexes. The single crystal X-ray diffraction measurements of [Mn(⍺-NaiEt)₂(NCS)₂] (⍺-NaiEt = 1-ethyl-2-(naphthyl-⍺-azo)imidazole) confirm the tetrahedrally coordinated MnN₄ structure of the complex. Cyclic voltammetry exhibits Mn(III)/Mn(II) couple along with azo reductions. |
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| Language |
en_US
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| Publisher |
CSIR
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| Relation |
Int. Cl. ⁸ C07F13/00
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| Source |
IJCA Vol.46A(4) [April 2007]
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| Title |
2-(Naphthyl-⍺-azo)imidazole complexes of manganese(II). Single crystal X-ray structure of [Mn(⍺-NaiEt)₂(NCS)₂] (⍺-NaiEt = 1-ethyl-2-(naphthyl-⍺-azo)imidazole)
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| Type |
Article
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