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[Bmim]BF4-immobilized rhenium-catalyzed highly efficient oxygenation of aldimines to oxaziridines using solid peroxides as oxidants

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Title [Bmim]BF4-immobilized rhenium-catalyzed highly efficient oxygenation of aldimines to oxaziridines using solid peroxides as oxidants
 
Creator Jain, SL
Singhal, S
Sain, B
 
Subject Chemistry, Inorganic & Nuclear; Chemistry, Organic
 
Description Various rhenium-based catalysts immobilized in [bmim]BF4 were found to be efficient for oxygenation of various aldimines to the corresponding oxaziridines in excellent yields under mild conditions using solid peroxides like UHP, SPC and SPB as oxidants. Among the various rhenium-based catalysts studied, MTO was found to be most efficient. The reusability and recyclability of MTO immobilized in [bmim]BF4 was established by using it for three subsequent cycles for oxygenation of benzylidine-tert-butylamine using UHP as oxidant. (C) 2007 Elsevier B.V. All rights reserved.
 
Publisher ELSEVIER SCIENCE SALAUSANNEPO BOX 564, 1001 LAUSANNE, SWITZERLAND
 
Date 2011-09-21T08:57:08Z
2011-09-21T08:57:08Z
2007
 
Type Article
 
Identifier JOURNAL OF ORGANOMETALLIC CHEMISTRY
0022-328X
http://hdl.handle.net/123456789/20199
 
Language English