Temperature-dependent isomerisation versus net fragmentation of secondary allylic alcohols with Grubbs' catalyst
Metadata of CSIR Papers
View Archive Info| Field | Value | |
| Title |
Temperature-dependent isomerisation versus net fragmentation of secondary allylic alcohols with Grubbs' catalyst
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| Creator |
Gurjar, MK
Yakambram, P |
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| Subject |
Chemistry, Organic
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| Description |
Secondary allylic alcohols with 10 mol% of Grubbs catalyst in refluxing toluene/1,2-dichloroethane undergo isomerisation to ethyl ketones whereas with 100 mol% of Grubbs catalyst at room temperature, a net fragmentation reaction with the loss of a carbon atom occurs, to provide a methyl ketone. Probable mechanisms are described. (C) 2001 Elsevier Science Ltd. All rights reserved.
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| Publisher |
PERGAMON-ELSEVIER SCIENCE LTDOXFORDTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
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| Date |
2011-09-24T08:35:37Z
2011-09-24T08:35:37Z 2001 |
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| Type |
Article
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| Identifier |
TETRAHEDRON LETTERS
0040-4039 http://hdl.handle.net/123456789/24055 |
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| Language |
English
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