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Synthesis and characterization of ferrierite-type zeolite in the presence of nonionic surfactants

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Title Synthesis and characterization of ferrierite-type zeolite in the presence of nonionic surfactants
 
Creator Khomane, RB
Kulkarni, BD
Ahedi, RK
 
Subject Chemistry, Physical
 
Description Pure-phase ferrierite (FER) zeolite has been synthesized in the presence of small amounts of nonionic surfactants, Tween 20 and Tween 80. The input SiO2/Al2O3 molar ratio has been varied over a range of 25 to 150. The results confirm that a small amount of pyrrolidine acts as a template and is necessary. The effects of varying concentration of surfactant on ferrierite crystallization and output SiO2/Al2O3 molar ratio are reported. The results also show that in the absence of pyrrolidine, ZSM-5 cocrystallized with FER, whereas in the absence of a nonionic surfactant the yield and crystallization of FER are very poor. The XRF analysis shows the changes in SiO2/Al2O3 output molar ratios as the surfactant concentration changes. The XRD data show that the samples are fully crystalline and pure. The TG/DTA of the sample shows its structural stability. The scanning electron microscopy results show changes in particle size with varying concentration of nonionic surfactant. (C) 2001 Academic Press.
 
Publisher ACADEMIC PRESS INCSAN DIEGO525 B ST, STE 1900, SAN DIEGO, CA 92101-4495 USA
 
Date 2011-09-24T08:49:39Z
2011-09-24T08:49:39Z
2001
 
Type Article
 
Identifier JOURNAL OF COLLOID AND INTERFACE SCIENCE
0021-9797
http://hdl.handle.net/123456789/24083
 
Language English