Efficient liquid phase acylation of alcohols over basic ETS-10 molecular sieves
Metadata of CSIR Papers
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| Title |
Efficient liquid phase acylation of alcohols over basic ETS-10 molecular sieves
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| Creator |
Waghmode, SB
Thakur, VV Sudalai, A Sivasanker, S |
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| Subject |
Chemistry, Organic
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| Description |
Acylation of alcohols with acetic acid can be carried out efficiently in the liquid phase over microporous titanosilicate ETS-10-type catalysts. The reaction was studied over ETS-10 exchanged with, Li, Na, K, Rb, Cs, Ba and H ions. Activity for acylation of primary alcohols depends on the exchanged alkali ion and increases in the order Li<Na<K<Ba <similar to> H similar to Rb similar to Cs-ETS-10. These molecular sieves are also suitable for the acylation of secondary alcohols and esterification with long chain carboxylic acids. (C) 2001 Elsevier Science Ltd. All rights reserved.
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| Publisher |
PERGAMON-ELSEVIER SCIENCE LTDOXFORDTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
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| Date |
2011-09-24T08:50:40Z
2011-09-24T08:50:40Z 2001 |
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| Type |
Article
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| Identifier |
TETRAHEDRON LETTERS
0040-4039 http://hdl.handle.net/123456789/24085 |
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| Language |
English
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