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Copolymerization of ethylene with aromatic vinyl monomers using metallocenes

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Title Copolymerization of ethylene with aromatic vinyl monomers using metallocenes
 
Creator Kumar, KR
Sivaram, S
 
Subject Polymer Science
 
Description Copolymerization of ethylene with styrene, allyl benzene and 4-phenyl-1-butene was examined using different metallocene catalysts. We separated the bulky phenyl group of styrene from its double bond using methylene spacers and studied the effect on its copolymerization behaviour with ethylene. The extent of incorporation of the comonomer is in the order 4-phenyl-1-butene > allyl benzene > styrene for all catalysts. The comonomer incorporation was found to be less than 10 mol% under the experimental conditions employed in the present study. (C) 2001 Society of Chemical Industry.
 
Publisher JOHN WILEY & SONS LTDW SUSSEXBAFFINS LANE CHICHESTER, W SUSSEX PO19 1UD, ENGLAND
 
Date 2011-09-24T09:01:11Z
2011-09-24T09:01:11Z
2001
 
Type Article
 
Identifier POLYMER INTERNATIONAL
0959-8103
http://hdl.handle.net/123456789/24106
 
Language English