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Calcium complexation by low molecular weight dicarboxycellulose in aqueous solution

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Title Calcium complexation by low molecular weight dicarboxycellulose in aqueous solution
 
Creator Varma, AJ
Chavan, VB
 
Subject Chemistry, Applied; Chemistry, Organic; Polymer Science
 
Description Carbohydrate polymers having the ability to complex calcium ions are of commercial interest. The effects of molecular weight and neighbouring carboxylate functional groups on a cellulose chain have been reported in this paper. High molecular weight sodium carboxymethylcellulose (viscosity of 2% solution 12 cP) was found to be marginally superior to low molecular weight sodium dicarboxycellulose (viscosity of 2% solution 1.1 cP) in its calcium complexing ability. Thus the sterically favourable effects of the neighbouring carboxylate groups can be offset by viscosity effects; both these are therefore important parameters in deciding the calcium complexing ability of a polymer. (C) 2001 Elsevier Science Ltd. All rights reserved.
 
Publisher ELSEVIER SCI LTDOXFORDTHE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, OXON, ENGLAND
 
Date 2011-09-24T09:11:11Z
2011-09-24T09:11:11Z
2001
 
Type Article
 
Identifier CARBOHYDRATE POLYMERS
0144-8617
http://hdl.handle.net/123456789/24126
 
Language English