A comparative study on the catalytic activity of ZnO modified zeolites in the synthesis of alkylpyrazines
Metadata of CSIR Papers
View Archive Info| Field | Value | |
| Title |
A comparative study on the catalytic activity of ZnO modified zeolites in the synthesis of alkylpyrazines
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| Creator |
Anand, R
Jyothi, TM Rao, BS |
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| Subject |
Chemistry, Physical; Environmental Sciences
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| Description |
The vapor phase condensation reaction of monoethanolamine (MEA) has been carried out over three ZnO-modified zeolite catalysts in the temperature range 280-400 degreesC. Ethylpyrazine was formed as the major product in the cases of ZnO-ZSM-5 and ZnO-FER, whereas pyrazine was formed as the major product in the case of ZnO-MOR. Moreover, we observed with ZnO-MOR a large amount of lower boilers which included methylamine, aziridine, ethylamine and ethylenediamine. The formation of DABCO was appreciable over ZnO-MOR; however, it becomes less probable over the other two catalysts, due to their higher dehydrogenation activity. The stability of these catalyst systems in the conversion of MEA followed the order: ZnO-ZSM-5 > ZnO-MOR > ZnO-FER. (C) 2001 Elsevier Science B.V. All rights reserved.
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| Publisher |
ELSEVIER SCIENCE BVAMSTERDAMPO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS
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| Date |
2011-09-24T09:15:42Z
2011-09-24T09:15:42Z 2001 |
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| Type |
Article
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| Identifier |
APPLIED CATALYSIS A-GENERAL
0926-860X http://hdl.handle.net/123456789/24135 |
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| Language |
English
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