Oxidative dehydrogenation of ethylene glycol into glyoxal over phosphorus-doped ferric molybdate catalyst
Metadata of CSIR Papers
View Archive Info| Field | Value | |
| Title |
Oxidative dehydrogenation of ethylene glycol into glyoxal over phosphorus-doped ferric molybdate catalyst
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| Creator |
Chumbhale, VR
Awasarkar, PA |
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| Subject |
Chemistry, Physical; Environmental Sciences
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| Description |
Test data for the catalytic oxidation of ethylene glycol (EG) into glyoxal obtained with a laboratory continuous flow tubular reactor are reported. A ferric molybdate catalyst modified with triammonium phosphate was used. Reaction parameters (temperature. contact time) affect the product distribution. The yield of glyoxal for the Fe-Mo-P catalyst was 43.3% at 88.9% conversion, whereas the corresponding values for the Fe-Mo (unmodified catalyst) were 20.5 and 97.2%. The addition of phosphorus formed a new Fe2MoP12 phase which restrains the reaction pathway towards carbon oxides. (C) 2001 Elsevier Science B.V. All rights reserved.
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| Publisher |
ELSEVIER SCIENCE BVAMSTERDAMPO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS
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| Date |
2011-09-24T09:32:13Z
2011-09-24T09:32:13Z 2001 |
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| Type |
Article
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| Identifier |
APPLIED CATALYSIS A-GENERAL
0926-860X http://hdl.handle.net/123456789/24168 |
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| Language |
English
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