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Formation and stabilization of gold nanoparticles in organo-functionalized MCM-41 mesoporous materials and their catalytic applications

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Title Formation and stabilization of gold nanoparticles in organo-functionalized MCM-41 mesoporous materials and their catalytic applications
 
Creator Patra, CR
Ghosh, A
Mukherjee, P
Sastry, M
Kumar, R
 
Subject Chemistry, Physical
 
Description A new process for the synthesis and stabilization of gold nanoparticles within the cavities of propylamine functionalized mesoporous MCM-41 material is described wherein silanol groups present on the inner surface of the mesoporous silica reduce aqueous chloroaurate ions to form the Au nanoparticles, and the amine groups anchor the nanoparticles thus formed in the inner surface of the cavities. The nano-Au-NH2-MCM-41 hybrid material was characterized by XRD, UV-Vis spectroscopy, EDX, TG-DTA and N-2 adsorption measurements. Further, this nano-Au-NH2-MCM-41 material shows promising catalytic activity and selectivity in the hydrogenation of styrene to ethylbenzene.
 
Publisher ELSEVIER SCIENCE BVAMSTERDAMSARA BURGERHARTSTRAAT 25, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS
 
Date 2011-09-24T09:40:44Z
2011-09-24T09:40:44Z
2002
 
Type Proceedings Paper
 
Identifier NANOPOROUS MATERIALS III
0-444-51113-X
0167-2991
http://hdl.handle.net/123456789/24185
 
Language English