A systematic study on the reactivity of Lewis acid-base complexes through the local hard-soft acid-base principle
Metadata of CSIR Papers
View Archive Info| Field | Value | |
| Title |
A systematic study on the reactivity of Lewis acid-base complexes through the local hard-soft acid-base principle
|
|
| Creator |
Chandrakumar, KRS
Pal, S |
|
| Subject |
Chemistry, Physical; Physics, Atomic, Molecular & Chemical
|
|
| Description |
The present paper addresses the stability of Lewis acid-base complexes using the recently developed local hard-soft acid-base (HSAB) principle. The principal role of electronegativity equalization and the charge redistribution process in stabilizing the complexes is demonstrated. The soft-soft and hard-hard types of interactions are well distinguished. by the electron transfer parameter. The effect of correlation on the reactivity descriptors and subsequently on the soft-soft as well as hard-hard interactions has been studied. The validity of the present model in calculating the interaction energy of these complexes with varying degrees of strength is demonstrated.
|
|
| Publisher |
AMER CHEMICAL SOCWASHINGTON1155 16TH ST, NW, WASHINGTON, DC 20036 USA
|
|
| Date |
2011-09-24T09:52:15Z
2011-09-24T09:52:15Z 2002 |
|
| Type |
Article
|
|
| Identifier |
JOURNAL OF PHYSICAL CHEMISTRY A
1089-5639 http://hdl.handle.net/123456789/24208 |
|
| Language |
English
|
|