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POLAROGRAPHIC DETERMINATION OF TRACE AMOUNT OF TITANIUM USING CATALYTIC CURRENT IN THE PRESENCE OF CHLORATE

IR@NAL: CSIR-National Aerospace Laboratories, Bangalore

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Title POLAROGRAPHIC DETERMINATION OF TRACE AMOUNT OF TITANIUM USING CATALYTIC CURRENT IN THE PRESENCE OF CHLORATE
 
Creator Basu, Bharathibai J
Rajagopalan, SR
 
Subject Composite Materials
 
Description Titanium (IV) oxalate complexes are reduced catalyticaUy in the presence of chlorate and this gives rise to an enhancement in sensitivity. Experimental conditions such as acid strength and the concentrations of chlorate, oxalate etc. were standardized to extend the linearity of calibration graph to low titanium concentrations. The interfering effect of other metal ions like Fe(lIl), Mo(VI), Cu(II), Bi(III), Pb(ll), Cd(ll), Ni(ll), Cr(III), Cr(Vl) and Zn(lI) on the catalytic current of Ti(IV) was investigated. The detection limit for the determination of Ti(IV) by this method was found to be 5 ngml I.
 
Publisher Elsevier Publisher
 
Date 1993
 
Type Journal Article
PeerReviewed
 
Format application/pdf
 
Identifier http://nal-ir.nal.res.in/9793/1/BulletinElectroChemistry%2D1993.pdf
Basu, Bharathibai J and Rajagopalan, SR (1993) POLAROGRAPHIC DETERMINATION OF TRACE AMOUNT OF TITANIUM USING CATALYTIC CURRENT IN THE PRESENCE OF CHLORATE. Bulletin of Electrochemistry, 9 (1). pp. 35-37.
 
Relation http://nal-ir.nal.res.in/9793/