Epoxidation of olefins catalyzed by manganese(II) complexes of Schiff base ligand having N2O coordination sphere
IR@NISCAIR: CSIR-NISCAIR, New Delhi - ONLINE PERIODICALS REPOSITORY (NOPR)
View Archive Info| Field | Value | |
| Creator |
Guha, Averi
Das, Debasis |
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| Date |
2011-11-01T04:54:34Z
2011-11-01T04:54:34Z 2011-11 |
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| Identifier |
0975-0975(Online); 0376-4710(Print)
http://hdl.handle.net/123456789/12993 |
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| Description |
1574-1578
Three mononuclear manganese(II) complexes having two N<sub>2</sub>O coordination spheres have been examined as catalysts for epoxidation of (<i>E</i>)-stilbene and styrene using PhIO and NaOCl as terminal oxidants in four different solvents. The catalytic efficiency of the complexes are observed to be influenced not only by their own structural features but also by the nature of terminal oxidant, substrate as well as the solvents. Epoxidation proceeds with the formation of two different intermediates, O=Mn(IV)(L)(X) and Cl-O-Mn(II)(L)(X) [X=NO<sub>3</sub>/SCN/N(CN)<sub>2</sub>], in presence of PhIO and NaOCl respectively. Amongst the solvents, acetonitrile is found to be the most suitable. |
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| Language |
en_US
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| Publisher |
NISCAIR-CSIR, India
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| Rights |
<img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
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| Source |
IJC-A Vol.50A(11) [November 2011]
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| Subject |
Epoxidation
Solvent effects Terminal oxidants Olefins Manganese Catalysts Schiff bases |
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| Title |
Epoxidation of olefins catalyzed by manganese(II) complexes of Schiff base ligand having N2O coordination sphere
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| Type |
Article
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