Synthesis of nano-MgO and identification of the destructive product of its reaction with 2-chloroethyl phenyl sulfide
IR@NISCAIR: CSIR-NISCAIR, New Delhi - ONLINE PERIODICALS REPOSITORY (NOPR)
View Archive Info| Field | Value | |
| Creator |
Maddah, Bozorgmehr
Aminifar, Amir Chalabi, Hossein |
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| Date |
2011-11-01T04:55:42Z
2011-11-01T04:55:42Z 2011-11 |
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| Identifier |
0975-0975(Online); 0376-4710(Print)
http://hdl.handle.net/123456789/12995 |
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| Description |
1587-1591
Nanocrystalline magnesium oxide has been prepared by the sol-gel method and characterized by X-ray diffraction, N<sub>2</sub>-BET, SEM and infrared spectroscopic techniques. Results confirm the formation of nano-MgO materials with crystallite size in the range of 5-20 nm and surface area of 336-556 m<sup>2</sup>/g. The product has been tested as destructive adsorbent for the decontamination of (2-chloroethyl) phenyl sulfide, a mimic of bis(2-chloroethyl) sulfide ("HD" or mustard gas). Destructive adsorbent reaction has been carried out in heptane and methanol media and investigated by GC-FID and GC-MS techniques. Reaction rate in heptane is observed to be higher than in methanol. It seems that a nonpolar media aids material transfer to the reactive surface sites without blocking these sites. |
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| Language |
en_US
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| Publisher |
NISCAIR-CSIR, India
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| Rights |
<img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
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| Source |
IJC-A Vol.50A(11) [November 2011]
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| Subject |
Nanomaterials
Decontamination reaction Magnesium oxide Destructive adsorbent |
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| Title |
Synthesis of nano-MgO and identification of the destructive product of its reaction with 2-chloroethyl phenyl sulfide
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| Type |
Article
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