A green chemical approach for the N-alkylation of aldoximes to form nitrones in organized aqueous media and their in situ cycloaddition with olefins
IR@IICB: CSIR-Indian Institute of Chemical Biology, Kolkata
View Archive Info| Field | Value | |
| Title |
A green chemical approach for the N-alkylation of aldoximes to
form nitrones in organized aqueous media and their in situ
cycloaddition with olefins
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| Creator |
Hota, Sandip K
Chatterjee, Amrita Bhattacharya, Pranab K Chattopadhyay, Partha |
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| Subject |
Chemistry
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| Description |
Aldoximes react with a,b-unsaturated carbonyl and sulfonyl compounds in organized aqueous
media (nanoreactor system) using dodecylbenzenesulfonic acid (DBSA) as surfactant to generate
N-alkylated nitrones, which undergo intermolecular cycloaddition in the same pot with
maleimides to give the desired cycloadduct in absence of any organic solvent and catalyst. Divinyl
sulfone was successfully used for both N-alkylation and intramolecular cycloaddition, affording
only one cycloadduct. This is a new example of green chemistry and provides a new aspect of
reactions in water.
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| Publisher |
Royal Society of Chemistry
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| Date |
2009
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://www.eprints.iicb.res.in/177/1/GREEN_CHEMISTRY%2C11(2)%2C169%2D176%2C2009[136].pdf
Hota, Sandip K and Chatterjee, Amrita and Bhattacharya, Pranab K and Chattopadhyay, Partha (2009) A green chemical approach for the N-alkylation of aldoximes to form nitrones in organized aqueous media and their in situ cycloaddition with olefins. Green Chemistry, 11 (2). pp. 169-176. |
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| Relation |
http://dx.doi.org/10.1039/b812290c
http://www.eprints.iicb.res.in/177/ |
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