General Route to 4a-Methylhydrofluorene Diterpenoids: Total Syntheses of (()-Taiwaniaquinones D and H, (()-Taiwaniaquinol B, (()-Dichroanal B, and (()-Dichroanone
IR@IICB: CSIR-Indian Institute of Chemical Biology, Kolkata
View Archive Info| Field | Value | |
| Title |
General Route to 4a-Methylhydrofluorene Diterpenoids: Total
Syntheses of (()-Taiwaniaquinones D and H, (()-Taiwaniaquinol B,
(()-Dichroanal B, and (()-Dichroanone
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| Creator |
Banerjee, Mainak
Mukhopadhyay, Ranjan Achari, Basudeb Banerjee, Asish Kr |
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| Subject |
Chemistry
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| Description |
A general and convergent route for the synthesis of the 4a-methylhydrofluorene diterpenoids has been
established through a common hexahydrofluorenone intermediate (10) obtained via Pd(0)-catalyzed
reductive cyclization of a substituted 2-(2-bromobenzyl) methylene cyclohexane (13). The strategy has
been successfully utilized for the synthesis of (()-taiwaniaquinones D (3) and H (5), (()-taiwaniaquinol
B (1), (()-dichroanal B (7), and (()-dichroanone (8).
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| Date |
2006
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://www.eprints.iicb.res.in/401/1/JOURNAL_OF_ORGANIC_CHEMISTRY%2C_71(_7)%2C_2787%2D2796_[113].pdf
Banerjee, Mainak and Mukhopadhyay, Ranjan and Achari, Basudeb and Banerjee, Asish Kr (2006) General Route to 4a-Methylhydrofluorene Diterpenoids: Total Syntheses of (()-Taiwaniaquinones D and H, (()-Taiwaniaquinol B, (()-Dichroanal B, and (()-Dichroanone. Journal of Organic Chemistry , 71 (7). pp. 2787-2796. |
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| Relation |
http://dx.doi.org/10.1021/jo052589w
http://www.eprints.iicb.res.in/401/ |
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