Mercuric Chloride and Iodide Mediated Cyclization of Tethered Alkynedithioacetals as a General Route to Five- and Six-Membered Rings: m Tuning of Regioselectivity by Alkyne Substitution
IR@IICB: CSIR-Indian Institute of Chemical Biology, Kolkata
View Archive Info| Field | Value | |
| Title |
Mercuric Chloride and Iodide Mediated Cyclization of Tethered Alkynedithioacetals as a General Route
to Five- and Six-Membered Rings: m Tuning of Regioselectivity by Alkyne
Substitution
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| Creator |
Biswas, Goutam
Ghorai, Subir Bhattacharjya, Anup |
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| Subject |
Chemistry
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| Description |
Mercuric chloride mediated cyclization of tethered alkynedithioacetals has been established as a general route to five- and six-membered
carbocycles and heterocycles. Substitution at the alkyne terminus leads to preferential formation of five-membered rings, whereas unsubstituted
alkynedithioacetals give six-membered rings as the major products. Mercuric iodide interrupts the reaction at the intermediate dithioacetal
stage.
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| Date |
2006
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://www.eprints.iicb.res.in/452/1/ORGANIC_LETTERS%2C_8(_2)%2C_313%2D316_[140].pdf
Biswas, Goutam and Ghorai, Subir and Bhattacharjya, Anup (2006) Mercuric Chloride and Iodide Mediated Cyclization of Tethered Alkynedithioacetals as a General Route to Five- and Six-Membered Rings: m Tuning of Regioselectivity by Alkyne Substitution. Organic Letters, 8 (2). pp. 313-316. |
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| Relation |
http://dx.doi.org/10.1021/ol0527274 CCC: $33.50
http://www.eprints.iicb.res.in/452/ |
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