Interaction of catechin with an iron(III) bis-benzimidazole diamide complex
IR@NISCAIR: CSIR-NISCAIR, New Delhi - ONLINE PERIODICALS REPOSITORY (NOPR)
View Archive Info| Field | Value | |
| Creator |
Tyagi, Nidhi
Mathur, Pavan |
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| Date |
2011-11-30T10:21:43Z
2011-11-30T10:21:43Z 2011-12 |
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| Identifier |
0975-0975(Online); 0376-4710(Print)
http://hdl.handle.net/123456789/13105 |
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| Description |
1703-1708
Bis-benzimidazole diamide ligand, 3,3'-thiobis-(N-((1H-benzo[d]imidazol-2-yl)methyl) propanamide [GBTPA = L] has been synthesized and utilized to prepare new Fe(III) complexes with exogenous anionic ligands, Cl¯and NO<sub>3</sub>¯. The complexes have been characterized by IR, UV-visible, cyclic voltammetry, EPR and mass spectrometry. Low temperature EPR spectra are characteristic of a rhombic complex undergoing an axial distortion. Redox chemistry of catechin and iron(III) chloride complex in dimethyl sulfoxide, shows that catechin binds with Fe(III) complex leading to a considerable loss of antioxidant activity. |
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| Language |
en_US
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| Publisher |
NISCAIR-CSIR, India
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| Rights |
<img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
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| Source |
IJC-A Vol.50A(12) [December 2011]
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| Subject |
Coordination chemistry
Iron Benzimidazole diamides Catechin Electrochemical studies |
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| Title |
Interaction of catechin with an iron(III) bis-benzimidazole diamide complex
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| Type |
Article
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