Preparation, characterization and catalytic application of some polyoxometalates with Keggin, Wells-Dawson and Preyssler structures
IR@NISCAIR: CSIR-NISCAIR, New Delhi - ONLINE PERIODICALS REPOSITORY (NOPR)
View Archive Info| Field | Value | |
| Creator |
Sheshmani, Shabnam
Fashapoyeh, Marzieh Arab Mirzaei, Masoud Rad, Bita Abedi Ghortolmesh, Somayeh Nouri Yousefi, Mohammad |
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| Date |
2011-11-30T10:23:33Z
2011-11-30T10:23:33Z 2011-12 |
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| Identifier |
0975-0975(Online); 0376-4710(Print)
http://hdl.handle.net/123456789/13108 |
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| Description |
1725-1729
Dibutylphthalate has been prepared<i> </i>via esterification reaction in the presence of some solid acidic catalysts. Transition metal polyoxometalates with Keggin (K<sub>3</sub>[PMo<sub>6</sub>W<sub>6</sub>O<sub>40</sub>], K<sub>3</sub>[PMo<sub>12</sub>O<sub>40</sub>], K<sub>4</sub>[SiMo<sub>12</sub>O<sub>40</sub>], K<sub>4</sub>[SiW<sub>12</sub>O<sub>40</sub>], Na<sub>7</sub>[PW<sub>11</sub>O<sub>39</sub>]), Wells-Dawson (K<sub>6</sub>[P<sub>2</sub>W<sub>18</sub>O<sub>62</sub>]), and Preyssler structures (K<sub>14</sub>[NaP<sub>5</sub>W<sub>30</sub>O<sub>110</sub>]) have been synthesized and characterized. The reactivity of these catalysts has been studied for the preparation of dibutylphtalate by esterification reaction of phthalic anhydride and 1-butanol. Among the various acidic catalyst used, K<sub>3</sub>[PMo<sub>6</sub>W<sub>6</sub>O<sub>40</sub>] showed the best reactivity and efficiency compared to other catalysts. |
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| Language |
en_US
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| Publisher |
NISCAIR-CSIR, India
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| Rights |
<img src='http://nopr.niscair.res.in/image/cc-license-sml.png'> <a href='http://creativecommons.org/licenses/by-nc-nd/2.5/in' target='_blank'>CC Attribution-Noncommercial-No Derivative Works 2.5 India</a>
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| Source |
IJC-A Vol.50A(12) [December 2011]
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| Subject |
Catalysts
Solid catalysts Polyoxometalates Keggin structure Wells-Dawson structure Preyssler structure Esterification Dibutylphthalate |
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| Title |
Preparation, characterization and catalytic application of some polyoxometalates with Keggin, Wells-Dawson and Preyssler structures
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| Type |
Article
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