Synthesis of novel acetates of b-caryophyllene under solvent-free Lewis acid catalysis
IR@IHBT: CSIR-Institute of Himalayan Bioresource Technology, Palampur
View Archive Info| Field | Value | |
| Title |
Synthesis of novel acetates of b-caryophyllene under solvent-free Lewis
acid catalysis
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| Creator |
Singh , Bikram
Jaitak, V Kaul, V K |
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| Subject |
Natural Product Chemistry
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| Description |
Acylation of bita-caryophyllene, a sesquiterpene hydrocarbon with acetic anhydride,
was carried out under mild catalytic conditions using Lewis acids such as
BF3. Et2O, ZnCl2, FeCl3, I2 and AlCl3 as catalysts. Among these, BF3. Et2O was
found to catalyse the reaction most efficiently, yielding three acylated products in
75% yield under solvent-free conditions. The structures were confirmed by NMR
and MS techniques.
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| Date |
2009
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://ihbt.csircentral.net/319/2/399_2009_Synthesis.pdf
Singh , Bikram and Jaitak, V and Kaul, V K (2009) Synthesis of novel acetates of b-caryophyllene under solvent-free Lewis acid catalysis. Natural Product Research , 23 (15). pp. 1445-1450. |
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| Relation |
http://ihbt.csircentral.net/319/
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