New Chiral Borohydride Based Reducing Agent : Asymmetric Reduction of 9-Anthryl Trifluoromethyl Ketone and Other Carbonyl Compounds
IR@IICB: CSIR-Indian Institute of Chemical Biology, Kolkata
View Archive Info| Field | Value | |
| Title |
New Chiral Borohydride Based Reducing Agent : Asymmetric Reduction of 9-Anthryl Trifluoromethyl Ketone and Other Carbonyl Compounds
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| Creator |
Maiti, Dilip K
Bhattacharya, Pranab K |
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| Subject |
Chemistry
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| Description |
(S)-(+)-2-(a-Hydroxybenzyl)benzimidazole (1) and (S)-(-)-2-
benzimidazole-1 -ethanol (2) were synthesised and converted to chiral borohydrides
which reduced prochiral ketones to the corresponding chiral alcohols in high yields
(80 to loo%, e.e. 42 to 95%). This is the first report of sodium borohydride
modified by 1,2-amino alcohol.
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| Date |
1998
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://www.eprints.iicb.res.in/824/1/SYNTHETIC_COMMUNICATIONS%2C_28(_1)%2C_99%2D108[63].pdf
Maiti, Dilip K and Bhattacharya, Pranab K (1998) New Chiral Borohydride Based Reducing Agent : Asymmetric Reduction of 9-Anthryl Trifluoromethyl Ketone and Other Carbonyl Compounds. Synthetic Communications, 28 (1). pp. 99-108. |
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| Relation |
http://dx.doi.org/10.1080/00397919808005078
http://www.eprints.iicb.res.in/824/ |
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