An expeditious protocol for sesquiterpene-cored functionalized arenes from S-(-)-citronellal
IR@CDRI: CSIR-Central Drug Research Institute, Lucknow
View Archive Info| Field | Value | |
| Creator |
Goel, Atul
Verma, Deepti |
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| Date |
2009-08-17T10:44:53Z
2009-08-17T10:44:53Z 2009 |
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| Identifier |
Tetrahedron Lett (2009) 50, 2086-2089
http://hdl.handle.net/123456789/478 |
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| Description |
An expeditious straightforward synthesis of sesquiterpene-cored arenes functionalized with electron-withdrawing or donating substituents is described and illustrated by Michael addition of S-(-)-citronellal on functionalized 2H-pyran-2-one in a single step at room temperature. The reaction was further generalized by synthesizing isoprenylated 9,10-dihydrophenanthrene-2-carbonitrile using 5,6-dihydro-2-oxo-4-sec-amino-2H-benzo[h]chromene-3-carbonitriles and S-(-)-citronellal under similar reaction conditions.
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| Format |
153920 bytes
application/pdf |
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| Language |
en
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| Relation |
CDRI Communication No. 7364
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| Subject |
Bisabolene
sesquiterpene 2H-pyran-2-ones citronellal ring transformation approach |
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| Title |
An expeditious protocol for sesquiterpene-cored functionalized arenes from S-(-)-citronellal
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| Type |
Article
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