Enantioselective synthesis of functionalized 1-benzoxepines by phenoxide ion-mediated 7-endo-tet carbocyclization of cyclic sulfates
IR@CDRI: CSIR-Central Drug Research Institute, Lucknow
View Archive Info| Field | Value | |
| Creator |
Das, S K
Dinda, S K Panda, Gautam |
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| Date |
2010-09-09T08:51:50Z
2010-09-09T08:51:50Z 2009 |
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| Identifier |
Eur. J. Org. Chem. 2009(2), 204-207
http://hdl.handle.net/123456789/585 |
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| Description |
Asymmetric synthesis of 2,3-disubstituted-1-benzoxepines is described. Key steps include Sharpless asymmetric dihydroxylation of trans-α,β-unsaturated esters and phenoxide ion-mediated intramolecular 7-endo-tet carbocyclization of syn-2,3-dihydroxy ester-derived cyclic sulphates.
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| Format |
164191 bytes
application/pdf |
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| Language |
en
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| Subject |
1-Benzoxepine
Sharpless asymmetric dihydroxylation Cyclic sulphate |
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| Title |
Enantioselective synthesis of functionalized 1-benzoxepines by phenoxide ion-mediated 7-endo-tet carbocyclization of cyclic sulfates
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| Type |
Article
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