Sequential Baylis–Hillman Reaction and Radical Cyclization of Furanose Derivatives: Expeditious Approach to Enantiopure Benzo-Fused Nine-Membered Oxacycles
IR@IICB: CSIR-Indian Institute of Chemical Biology, Kolkata
View Archive Info| Field | Value | |
| Title |
Sequential Baylis–Hillman Reaction and Radical Cyclization of Furanose Derivatives: Expeditious Approach to Enantiopure Benzo-Fused Nine-Membered Oxacycles
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| Creator |
Majhi, Tirtha Pada
Neogi, Arpita Ghosh, Soumen Mukherjee, Alok Kumar Chattopadhyay, Partha |
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| Subject |
Chemistry
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| Description |
A regioselective 9-endo-trig aryl radical cyclization of D-glucose derived diastereomeric Baylis–Hillman reaction products with Bu3SnH led to highly functionalized tricyclic benzannulated ethers incorporating cis- and trans-9,5 bicyclic systems in good yields. Degradation
of one of the products afforded an enantiopure multifunctionalized benzoxonine derivative.
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| Date |
2006
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://www.eprints.iicb.res.in/1090/1/TETRAHEDRON__Volume_62___Issue_51___Pages_12003%2D12010__[2].pdf
Majhi, Tirtha Pada and Neogi, Arpita and Ghosh, Soumen and Mukherjee, Alok Kumar and Chattopadhyay, Partha (2006) Sequential Baylis–Hillman Reaction and Radical Cyclization of Furanose Derivatives: Expeditious Approach to Enantiopure Benzo-Fused Nine-Membered Oxacycles. Tetrahedron, 62 (51). pp. 12003-12010. |
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| Relation |
http://dx.doi.org/10.1016/j.tet.2006.09.080
http://www.eprints.iicb.res.in/1090/ |
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