Iron oxide mediated direct C–H arylation/alkylation at α-position of cyclic aliphatic ethers
IR@IIIM: CSIR-Indian Institute of Integrative Medicine, Jammu
View Archive Info| Field | Value | |
| Title |
Iron oxide mediated direct C–H arylation/alkylation at α-position of cyclic aliphatic ethers
|
|
| Creator |
Singh, Parvinder Pal
Gudup, Satish Ambala, Srinivas Singh, Umed Dadhwal, Sumit Singh, Baldev Sawant, Sanghapal D. Vishwakarma, Ram A. |
|
| Subject |
Chemical Sciences
|
|
| Description |
We report a new and efficient iron oxide catalyzed crosscoupling reaction between organometallic species such as
alkyl/arylmagnesium halides or organolithium species and
a-hydrogen bearing cyclic aliphatic ethers via activation of
C(sp3)–H. This is the first example of iron oxide mediated direct C–C bond formation without expensive or toxic ligands.
|
|
| Date |
2011
|
|
| Type |
Article
PeerReviewed |
|
| Format |
application/pdf
|
|
| Identifier |
http://iiim.csircentral.net/280/1/10.1039c1cc11094b.pdf
Singh, Parvinder Pal and Gudup, Satish and Ambala, Srinivas and Singh, Umed and Dadhwal, Sumit and Singh, Baldev and Sawant, Sanghapal D. and Vishwakarma, Ram A. (2011) Iron oxide mediated direct C–H arylation/alkylation at α-position of cyclic aliphatic ethers. Chemical Communications, 47 (20). p. 5852. ISSN 1359-7345 |
|
| Relation |
http://dx.doi.org/10.1039/c1cc11094b
http://iiim.csircentral.net/280/ |
|