A mild and convenient procedure for the conversion of toxic beta-asarone into rare phenylpropanoids: 2,4,5-trimethoxycinnamaldehyde and gamma-asarone
IR@IHBT: CSIR-Institute of Himalayan Bioresource Technology, Palampur
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| Title |
A mild and convenient procedure for the conversion of toxic beta-asarone into rare phenylpropanoids: 2,4,5-trimethoxycinnamaldehyde and gamma-asarone
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| Creator |
Sinha, Arun K
Acharya , Ruchi Joshi, B P |
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| Subject |
Natural Product Chemistry
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| Description |
Oxidation of beta-asarone (2) with DDQ gave trans-2,4,5-trimethoxycinnainaldehyde (3), which on treatment with p-toluenesulfonyl hydrazine provided corresponding alpha,beta-unsaturated hydrazone derivative (4). Reduction of 4 with sodium borohydride in acetic acid afforded gamma-asarone (1) in 43% yield.
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| Publisher |
American Chemical Society, 1155 16TH ST, NW, Washington, DC 20036 USA
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| Date |
2002
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://ihbt.csircentral.net/365/1/64_A_A_Mild.pdf
Sinha, Arun K and Acharya , Ruchi and Joshi, B P (2002) A mild and convenient procedure for the conversion of toxic beta-asarone into rare phenylpropanoids: 2,4,5-trimethoxycinnamaldehyde and gamma-asarone. Journal of Natural Products , 65 (5). pp. 764-765. ISSN 0163-3864 |
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| Relation |
http://ihbt.csircentral.net/365/
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