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Yb(OTf)3 and ZrCl4 Mediated Rearrangement of Alkoxybenzyl Allyl Ethers into Aldehydes#

IR@IICT: CSIR-Indian Institute of Chemical Technology, Hyderabad

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Field Value
 
Creator RadhaKrishna, P
Reddy, Ch.G
Sharma, G.V.M
 
Date 2008-12-15T10:52:50Z
2008-12-15T10:52:50Z
2004
 
Identifier Letters in Organic Chemistry,Vol.1, 212-214p
http://hdl.handle.net/123456789/53
 
Description Lewis acid mediated rearrangement of alkoxybenzyl allyl ethers into aldehydes in moderate to good yields, catalysed either by Yb(OTf)3 or ZrCl4 is reported. The ZrCl4 catalysed transformation offers mild and easily adaptable clean reaction conditions and good yields of the products. Additionally, ZrCl4 catalysed rearrangement under solvent free conditions is an advantageous modification.
 
Subject Yb(OT0)3
ZrCl4
Solvent-free conditions
Lewis acid catalysed rearrangement
Aldehydes
Naphthalene derivatives
 
Title Yb(OTf)3 and ZrCl4 Mediated Rearrangement of Alkoxybenzyl Allyl Ethers into Aldehydes#
 
Type Article