Yb(OTf)3 and ZrCl4 Mediated Rearrangement of Alkoxybenzyl Allyl Ethers into Aldehydes#
IR@IICT: CSIR-Indian Institute of Chemical Technology, Hyderabad
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Creator |
RadhaKrishna, P
Reddy, Ch.G Sharma, G.V.M |
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Date |
2008-12-15T10:52:50Z
2008-12-15T10:52:50Z 2004 |
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Identifier |
Letters in Organic
Chemistry,Vol.1, 212-214p
http://hdl.handle.net/123456789/53 |
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Description |
Lewis acid mediated rearrangement of alkoxybenzyl allyl ethers into aldehydes in moderate to good yields, catalysed either by Yb(OTf)3 or ZrCl4 is reported. The ZrCl4 catalysed transformation offers mild and easily adaptable clean reaction conditions and good yields of the products. Additionally, ZrCl4 catalysed rearrangement under solvent free conditions is an advantageous modification.
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Subject |
Yb(OT0)3
ZrCl4 Solvent-free conditions Lewis acid catalysed rearrangement Aldehydes Naphthalene derivatives |
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Title |
Yb(OTf)3 and ZrCl4 Mediated Rearrangement of Alkoxybenzyl Allyl Ethers into Aldehydes#
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Type |
Article
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