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AlCl3,6H2O/KI/H2O/CH3CN : a new alternate system for dehydration of oximes and amides in hydrated media

IR@NEIST: CSIR-North East Institute of Science and Technology, Jorhat

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Title AlCl3,6H2O/KI/H2O/CH3CN : a new alternate system for dehydration of oximes and amides in hydrated media
 
Creator BORUAH , M
KONWAR , D
 
Subject Organic Chemistry
 
Description Dehydration of oximes and amides to nitriles was carried out using the AlCl3รข6H2O/KI/H2O/CH3CN system. It produced isoquinoline derivatives 8a-c (Bischler Naperialski reaction) when reacted with amides 7a-c in hydrated media. Also, the keto oximes produced anilides (Beckmann rearrangement) with the system under the same reaction conditions.
 
Date 2002
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://neist.csircentral.net/341/1/1026_JOC_2002_konwar.d.pdf
BORUAH , M and KONWAR , D (2002) AlCl3,6H2O/KI/H2O/CH3CN : a new alternate system for dehydration of oximes and amides in hydrated media. J Organic Chemistry, , 67. pp. 7138-7139.
 
Relation http://neist.csircentral.net/341/