Novel electrochemical synthesis and characterisation of poly(methyl vinylsilane) and its co-polymers
IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi
View Archive Info| Field | Value | |
| Title |
Novel electrochemical synthesis and characterisation
of poly(methyl vinylsilane) and its co-polymers
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| Creator |
Elangovan, M.
Muthukumaran, A. Anbukulandainathan, M. |
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| Subject |
Electroorganic
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| Description |
The electrochemical synthesis and characterisation of poly(methyl vinylsilane) and a series of poly(methyl vinylsilane-
co-metallocenes) network polymers are described in detail. This class of polymers are not accessible through
Wurtz coupling reaction and are however prepared by electro-reduction of dichloro methyl vinylsilane in a nonaqueous
system using aluminum electrodes in a single compartment cell. These polymers have been characterised using
UV, FTIR, XRD, SEM and NMR spectral techniques. Cyclic voltammetric studies of the above polymers reveal their
conducting behavior. These polymers show optical properties as explained from the results. Polymers of this type are
proposed as potential soluble precursors for SiC and metal doped SiC materials.
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| Publisher |
Elsevier
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| Date |
2005
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://cecri.csircentral.net/63/1/029-2005.pdf
Elangovan, M. and Muthukumaran, A. and Anbukulandainathan, M. (2005) Novel electrochemical synthesis and characterisation of poly(methyl vinylsilane) and its co-polymers. European Polymer Journal, 41 (10). pp. 2450-2460. |
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| Relation |
http://cecri.csircentral.net/63/
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