Electrochemistry of metals and semiconductors in fluoride media
IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi
View Archive Info| Field | Value | |
| Title |
Electrochemistry of metals and semiconductors in fluoride media
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| Creator |
Noel, M.
Suriyanarayanan, N. |
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| Subject |
Electroorganic
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| Description |
The electrochemical surface transformations and diverse applications of a variety of metals and semiconductors in a
wide range of fluoride media such as aqueous, non-aqueous media, liquid HF media, room temperature fluoride
melts and molten fluoride media with a melting range covering 50–1000 degree C are reviewed. Nickel shows excellent
corrosion resistance in the absence of water. The anodic performance of this metal in electrochemical
perfluorination and NF3 production is discussed. Compact carbon materials serve as anodes in fluorine generators.
In high temperature melts, they perform as consumable anodes. Graphitic carbon undergoes intercalation/
de-intercalation process and related battery applications. Cu/CuF2 couple is a good reference electrode. Pt and
vitreous carbon materials are the inert electrodes of choice for electro analytical applications. Electrodeposition of
Lithium as a non-dendritic uniform phase is important in Lithium metal based secondary batteries. High
temperature fluoride melts are used in electro-deposition of valve metals such as Nb, Ta, and Ti. The stability and
decomposition of fluoride complexes in these media are of interest.
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| Publisher |
Springer
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| Date |
2005
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://cecri.csircentral.net/75/1/037-2005.pdf
Noel, M. and Suriyanarayanan, N. (2005) Electrochemistry of metals and semiconductors in fluoride media. Journal of Applied Electrochemistry, 35 (1). pp. 49-60. |
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| Relation |
http://cecri.csircentral.net/75/
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