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Electron transfer studies through mixed self-assembled monolayers of thiophenol and thioctic acid

IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi

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Title Electron transfer studies through mixed self-assembled monolayers of thiophenol and thioctic acid
 
Creator Ramalechume, C.
Sheela, B.
Yegnaraman, V.
Mandal, A.B.
 
Subject Electrodics and Electrocatalysis
 
Description Mixed self-assembled monolayer of thiols were formed on the electrode surface using aromatic and aliphatic thiols and the modified interface were used to demonstrate charge trapping behavior at the modified interface. The electrode surface was modified by two schemes. In Scheme 1, electrode surface modified with methylene blue (MB) shows charge trapping behavior when contacts the electrolyte containing potassium ferricyanide. In Scheme 2, a redox-active bilayer is constructed using hexamineruthenium (II) chloride and methylene blue. This redox-active bilayer assembly exhibits unidirectional flow of current. � 2005 Elsevier B.V. All rights reserved.
 
Publisher Elsevier
 
Date 2005
 
Type Article
PeerReviewed
 
Format application/pdf
 
Identifier http://cecri.csircentral.net/98/1/048-2005.pdf
Ramalechume, C. and Sheela, B. and Yegnaraman, V. and Mandal, A.B. (2005) Electron transfer studies through mixed self-assembled monolayers of thiophenol and thioctic acid. Journal of Electroanalytical Chemistry, 580 (1). pp. 122-127.
 
Relation http://cecri.csircentral.net/98/