In-situ patterned intra-anode triple phase boundary in SOFC electroless anode: An enhancement of electrochemical performance
IR@CGCRI: CSIR-Central Glass and Ceramic Research Institute, Kolkata
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| Title |
In-situ patterned intra-anode triple phase boundary in SOFC electroless anode: An enhancement of electrochemical performance
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| Creator |
Mukhopadhyay, Madhumita
Mukhopadhyay, Jayanta Das Sharma, Abhijit Basu, Rajendra Nath |
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| Subject |
Electronics
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| Description |
Co-existence of intra-anode and conventional triple phase boundary (TPB) is reported for the first time in core (YSZ)-shell (Ni) electroless anode cermet. A mathematical model is proposed for determination of intra-anode TPB length and has been validated experimentally. Retention of longer intra-anode TPB even after repeated redox cycling is responsible for relatively lower conductivity degradation of such cermets. Existence of intra-anode TPB in electroless anode results in significant improvement of electrochemical performance. Single cells with electroless anode exhibit a current density of 2.5 A cm(-2) compared to cells with conventional anode (1.7A cm(-2)) at 800 degrees C, 0.7 V. Copyright (C) 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
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| Publisher |
Pergamon-Elsevier
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| Date |
2011-07
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://cgcri.csircentral.net/295/1/madhumita.pdf
Mukhopadhyay, Madhumita and Mukhopadhyay, Jayanta and Das Sharma, Abhijit and Basu, Rajendra Nath (2011) In-situ patterned intra-anode triple phase boundary in SOFC electroless anode: An enhancement of electrochemical performance. International Journal of Hydrogen Energy, 36 (13). pp. 7677-7682. ISSN 0360-3199 |
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| Relation |
http://cgcri.csircentral.net/295/
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