Electrochemical synthesis and characterization of conducting polymers using room temperature melt as an electrolyte
IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi
View Archive Info| Field | Value | |
| Title |
Electrochemical synthesis and characterization of conducting
polymers using room temperature melt as an electrolyte
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| Creator |
Geetha, S.
Trivedi, D.C. |
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| Subject |
Electrochemical Materials Science
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| Description |
Aromatic monomers can be polymerised using the chloroaluminate room temperature melt obtained by mixing 1:2 ratio of cetyl pyridinium
chloride and anhydrous aluminium chloride miscible in all proportions with organic solvents as an electrolyte. The chloroaluminate (AlCl4−) anion
generated in this melt having a tetrahedral symmetry with equal bond lengths and bond angles is the dopant to stabilize macrocation generated near
the vicinity of anode to yield better conducting and better ordered electronically conducting free standing polymer film. In this communication,
we discuss the polymers derived from benzene and pyrrole and their characterization by various techniques.
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| Publisher |
Elsevier
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| Date |
2005
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://cecri.csircentral.net/199/1/102-2005.pdf
Geetha, S. and Trivedi, D.C. (2005) Electrochemical synthesis and characterization of conducting polymers using room temperature melt as an electrolyte. Synthetic Metals, 155 (2). pp. 306-310. |
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| Relation |
http://cecri.csircentral.net/199/
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