A simple and regioselective a-bromination of alkyl aromatic compounds by two-phase electrolysis
IR@CECRI: CSIR-Central Electrochemical Research Institute, Karaikudi
View Archive Info| Field | Value | |
| Title |
A simple and regioselective a-bromination of alkyl
aromatic compounds by two-phase electrolysis
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| Creator |
Raju, T.
Kulangiappar, K. Anbukulandainathan, M. Muthukumaran, A. |
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| Subject |
Electroorganic
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| Description |
Electrochemical bromination of toluene and substituted toluenes by two-phase electrolysis yields the corresponding
a-brominated products. The reaction has been carried out in a single compartment cell with platinum electrodes at 0 �C in chloroform
using an aqueous sodium bromide solution (60%) containing a catalytic amount of HBr. Two-phase electrolysis results in high
yields (60–95%) of monobromo compounds with very high regioselectivity (>95%).
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| Publisher |
Elsevier
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| Date |
2005
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| Type |
Article
PeerReviewed |
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| Format |
application/pdf
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| Identifier |
http://cecri.csircentral.net/203/1/104-2005.pdf
Raju, T. and Kulangiappar, K. and Anbukulandainathan, M. and Muthukumaran, A. (2005) A simple and regioselective a-bromination of alkyl aromatic compounds by two-phase electrolysis. Tetrahedron Letters, 46 (41). pp. 7047-7050. |
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| Relation |
http://cecri.csircentral.net/203/
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